Experimental investigation of the initial regime in fingering electrodeposition: dispersion relation and velocity measurements.

نویسندگان

  • Matthias Schröter
  • Klaus Kassner
  • Ingo Rehberg
  • Josep Claret
  • Francesc Sagués
چکیده

Recently a fingering morphology, resembling the hydrodynamic Saffman-Taylor instability, was identified in the quasi-two-dimensional electrodeposition of copper. We present here measurements of the dispersion relation of the growing front. The instability is accompanied by gravity-driven convection rolls at the electrodes, which are examined using particle image velocimetry. While at the anode the theory presented by Chazalviel et al. [J. Electroanal. Chem. 407, 61 (1996)] describes the convection roll, the flow field at the cathode is more complicated because of the growing deposit. In particular, the analysis of the orientation of the velocity vectors reveals some lag of the development of the convection roll compared to the finger envelope.

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عنوان ژورنال:
  • Physical review. E, Statistical, nonlinear, and soft matter physics

دوره 65 4 Pt 1  شماره 

صفحات  -

تاریخ انتشار 2002